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Iron Table

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Iron Table

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Following this, iron was used in rails, boats, ships, aqueducts, and buildings, as well as in iron cylinders in steam engines. French, Spanish, Italian and German refer to railways as iron road.

Steel with smaller carbon content than pig iron but more than wrought iron was first produced in antiquity by using a bloomery.

These methods were specialized, and so steel did not become a major commodity until the s. New methods of producing it by carburizing bars of iron in the cementation process were devised in the 17th century.

In the Industrial Revolution , new methods of producing bar iron without charcoal were devised and these were later applied to produce steel. In the late s, Henry Bessemer invented a new steelmaking process, involving blowing air through molten pig iron, to produce mild steel.

This made steel much more economical, thereby leading to wrought iron no longer being produced in large quantities.

In , Antoine Lavoisier used the reaction of water steam with metallic iron inside an incandescent iron tube to produce hydrogen in his experiments leading to the demonstration of the conservation of mass , which was instrumental in changing chemistry from a qualitative science to a quantitative one.

Iron plays a certain role in mythology and has found various usage as a metaphor and in folklore. The Greek poet Hesiod 's Works and Days lines — lists different ages of man named after metals like gold, silver, bronze and iron to account for successive ages of humanity.

The Virtues, in despair, quit the earth; and the depravity of man becomes universal and complete. Hard steel succeeded then. An example of the importance of iron's symbolic role may be found in the German Campaign of Berlin iron jewellery reached its peak production between and , when the Prussian royal family urged citizens to donate gold and silver jewellery for military funding.

The inscription Gold gab ich für Eisen I gave gold for iron was used as well in later war efforts. Nowadays, the industrial production of iron or steel consists of two main stages.

In the first stage, iron ore is reduced with coke in a blast furnace , and the molten metal is separated from gross impurities such as silicate minerals.

This stage yields an alloy— pig iron —that contains relatively large amounts of carbon. In the second stage, the amount of carbon in the pig iron is lowered by oxidation to yield wrought iron, steel, or cast iron.

The blast furnace is loaded with iron ores, usually hematite Fe 2 O 3 or magnetite Fe 3 O 4 , together with coke coal that has been separately baked to remove volatile components.

Some iron in the high-temperature lower region of the furnace reacts directly with the coke: []. A flux such as limestone calcium carbonate or dolomite calcium-magnesium carbonate is also added to the furnace's load.

Its purpose is to remove silicaceous minerals in the ore, which would otherwise clog the furnace. The heat of the furnace decomposes the carbonates to calcium oxide , which reacts with any excess silica to form a slag composed of calcium silicate CaSiO 3 or other products.

At the furnace's temperature, the metal and the slag are both molten. They collect at the bottom as two immiscible liquid layers with the slag on top , that are then easily separated.

The high level of carbon makes it relatively weak and brittle. Reducing the amount of carbon to 0. A great variety of steel articles can then be made by cold working , hot rolling , forging , machining , etc.

Removing the other impurities, instead, results in cast iron, which is used to cast articles in foundries ; for example stoves, pipes, radiators, lamp-posts, and rails.

Steel products often undergo various heat treatments after they are forged to shape. It makes the steel softer and more workable.

Owing to environmental concerns, alternative methods of processing iron have been developed. Natural gas is partially oxidized with heat and a catalyst : [].

Iron ore is then treated with these gases in a furnace, producing solid sponge iron: []. Silica is removed by adding a limestone flux as described above.

Ignition of a mixture of aluminium powder and iron oxide yields metallic iron via the thermite reaction :. Various processes have been used for this, including finery forges , puddling furnaces, Bessemer converters , open hearth furnaces , basic oxygen furnaces , and electric arc furnaces.

In all cases, the objective is to oxidize some or all of the carbon, together with other impurities. On the other hand, other metals may be added to make alloy steels.

Its low cost and high strength often make it the material of choice material to withstand stress or transmit forces, such as the construction of machinery and machine tools , rails , automobiles , ship hulls , concrete reinforcing bars , and the load-carrying framework of buildings.

Since pure iron is quite soft, it is most commonly combined with alloying elements to make steel.

The mechanical properties of iron and its alloys are extremely relevant to their structural applications. Those properties can be evaluated in various ways, including the Brinell test , the Rockwell test and the Vickers hardness test.

The properties of pure iron are often used to calibrate measurements or to compare tests. An increase in the carbon content will cause a significant increase in the hardness and tensile strength of iron.

Maximum hardness of 65 R c is achieved with a 0. This form of iron is used in the type of stainless steel used for making cutlery, and hospital and food-service equipment.

Commercially available iron is classified based on purity and the abundance of additives. Pig iron has 3.

Pig iron is not a saleable product, but rather an intermediate step in the production of cast iron and steel. The broken surface of a white cast iron is full of fine facets of the broken iron carbide, a very pale, silvery, shiny material, hence the appellation.

Cooling a mixture of iron with 0. Rapid cooling, on the other hand, does not allow time for this separation and creates hard and brittle martensite.

The steel can then be tempered by reheating to a temperature in between, changing the proportions of pearlite and martensite. The end product below 0.

In gray iron the carbon exists as separate, fine flakes of graphite , and also renders the material brittle due to the sharp edged flakes of graphite that produce stress concentration sites within the material.

Wrought iron contains less than 0. If honed to an edge, it loses it quickly. Wrought iron is characterized by the presence of fine fibers of slag entrapped within the metal.

Wrought iron is more corrosion resistant than steel. It has been almost completely replaced by mild steel for traditional "wrought iron" products and blacksmithing.

Mild steel corrodes more readily than wrought iron, but is cheaper and more widely available. Carbon steel contains 2.

Alloy steels contain varying amounts of carbon as well as other metals, such as chromium , vanadium , molybdenum , nickel, tungsten , etc.

Their alloy content raises their cost, and so they are usually only employed for specialist uses. One common alloy steel, though, is stainless steel.

Recent developments in ferrous metallurgy have produced a growing range of microalloyed steels, also termed ' HSLA ' or high-strength, low alloy steels, containing tiny additions to produce high strengths and often spectacular toughness at minimal cost.

Apart from traditional applications, iron is also used for protection from ionizing radiation. Although it is lighter than another traditional protection material, lead , it is much stronger mechanically.

The attenuation of radiation as a function of energy is shown in the graph. The mechanism of the rusting of iron is as follows: [].

The electrolyte is usually iron II sulfate in urban areas formed when atmospheric sulfur dioxide attacks iron , and salt particles in the atmosphere in seaside areas.

Although the dominant use of iron is in metallurgy, iron compounds are also pervasive in industry. Iron catalysts are traditionally used in the Haber-Bosch process for the production of ammonia and the Fischer-Tropsch process for conversion of carbon monoxide to hydrocarbons for fuels and lubricants.

Iron III oxide mixed with aluminium powder can be ignited to create a thermite reaction , used in welding large iron parts like rails and purifying ores.

Iron III oxide and oxyhidroxide are used as reddish and ocher pigments. Iron III chloride finds use in water purification and sewage treatment , in the dyeing of cloth, as a coloring agent in paints, as an additive in animal feed, and as an etchant for copper in the manufacture of printed circuit boards.

Iron II sulfate is used as a precursor to other iron compounds. It is also used to reduce chromate in cement. It is used to fortify foods and treat iron deficiency anemia.

Iron III sulfate is used in settling minute sewage particles in tank water. Iron II chloride is used as a reducing flocculating agent, in the formation of iron complexes and magnetic iron oxides, and as a reducing agent in organic synthesis.

Iron is required for life. Iron-containing proteins participate in transport, storage and used of oxygen. Examples of iron-containing proteins in higher organisms include hemoglobin, cytochrome see high-valent iron , and catalase.

Iron acquisition poses a problem for aerobic organisms because ferric iron is poorly soluble near neutral pH.

Thus, these organisms have developed means to absorb iron as complexes, sometimes taking up ferrous iron before oxidising it back to ferric iron.

After uptake in human cells , iron storage is precisely regulated. The most commonly known and studied bioinorganic iron compounds biological iron molecules are the heme proteins : examples are hemoglobin , myoglobin , and cytochrome P Some examples of iron metalloproteins are ferritin and rubredoxin.

Hemoglobin is an oxygen carrier that occurs in red blood cells and contributes their color, transporting oxygen in the arteries from the lungs to the muscles where it is transferred to myoglobin , which stores it until it is needed for the metabolic oxidation of glucose , generating energy.

In this configuration, the sixth coordination site reserved for the oxygen is blocked by another histidine residue. When deoxyhemoglobin picks up an oxygen molecule, this histidine residue moves away and returns once the oxygen is securely attached to form a hydrogen bond with it.

This results in a movement of all the protein chains that leads to the other subunits of hemoglobin changing shape to a form with larger oxygen affinity.

Thus, when deoxyhemoglobin takes up oxygen, its affinity for more oxygen increases, and vice versa. Thus, while hemoglobin is almost saturated with oxygen in the high partial pressures of oxygen found in the lungs, its affinity for oxygen is much lower than that of myoglobin, which oxygenates even at low partial pressures of oxygen found in muscle tissue.

Carbon monoxide and phosphorus trifluoride are poisonous to humans because they bind to hemoglobin similarly to oxygen, but with much more strength, so that oxygen can no longer be transported throughout the body.

Hemoglobin bound to carbon monoxide is known as carboxyhemoglobin. This effect also plays a minor role in the toxicity of cyanide , but there the major effect is by far its interference with the proper functioning of the electron transport protein cytochrome a.

The sixth coordination site is then occupied by either another imidazole nitrogen or a methionine sulfur, so that these proteins are largely inert to oxygen — with the exception of cytochrome a, which bonds directly to oxygen and thus is very easily poisoned by cyanide.

Since the reduction potential of each step is slightly greater than the previous one, the energy is released step-by-step and can thus be stored in adenosine triphosphate.

Cytochrome a is slightly distinct, as it occurs at the mitochondrial membrane, binds directly to oxygen, and transports protons as well as electrons, as follows: [].

These have one, two, four, or eight iron atoms that are each approximately tetrahedrally coordinated to four sulfur atoms; because of this tetrahedral coordination, they always have high-spin iron.

The simplest of such compounds is rubredoxin , which has only one iron atom coordinated to four sulfur atoms from cysteine residues in the surrounding peptide chains.

Another important class of iron-sulfur proteins is the ferredoxins , which have multiple iron atoms.

Transferrin does not belong to either of these classes. The ability of sea mussels to maintain their grip on rocks in the ocean is facilitated by their use of organometallic iron-based bonds in their protein-rich cuticles.

Based on synthetic replicas, the presence of iron in these structures increased elastic modulus times, tensile strength 58 times, and toughness 92 times.

The amount of stress required to permanently damage them increased 76 times. Iron is pervasive, but particularly rich sources of dietary iron include red meat , oysters , lentils , beans , poultry , fish , leaf vegetables , watercress , tofu , chickpeas , black-eyed peas , and blackstrap molasses.

Iron provided by dietary supplements is often found as iron II fumarate , although iron II sulfate is cheaper and is absorbed equally well.

Iron is most available to the body when chelated to amino acids [] and is also available for use as a common iron supplement. Glycine , the least expensive amino acid, is most often used to produce iron glycinate supplements.

The U. For men the EAR is 6. The RDA is For men, 8. RDAs are higher than EARs so as to identify amounts that will cover people with higher than average requirements.

As for safety, the IOM also sets Tolerable upper intake levels ULs for vitamins and minerals when evidence is sufficient. The PRIs are higher than the U.

RDAs, with the exception of pregnancy. Infants may require iron supplements if they are bottle-fed cow's milk. For U. Iron deficiency is the most common nutritional deficiency in the world.

Most cases of iron-deficiency anemia are mild, but if not treated can cause problems like fast or irregular heartbeat, complications during pregnancy, and delayed growth in infants and children.

Iron uptake is tightly regulated by the human body, which has no regulated physiological means of excreting iron.

Only small amounts of iron are lost daily due to mucosal and skin epithelial cell sloughing, so control of iron levels is primarily accomplished by regulating uptake.

For this reason, people should not take iron supplements unless they suffer from iron deficiency and have consulted a doctor.

Hemochromatosis is estimated to be the cause of 0. Overdoses of ingested iron can cause excessive levels of free iron in the blood.

High blood levels of free ferrous iron react with peroxides to produce highly reactive free radicals that can damage DNA , proteins , lipids , and other cellular components.

Iron toxicity occurs when the cell contains free iron, which generally occurs when iron levels exceed the availability of transferrin to bind the iron.

Damage to the cells of the gastrointestinal tract can also prevent them from regulating iron absorption, leading to further increases in blood levels.

Iron typically damages cells in the heart , liver and elsewhere, causing adverse effects that include coma , metabolic acidosis , shock , liver failure , coagulopathy , adult respiratory distress syndrome , long-term organ damage, and even death.

The medical management of iron toxicity is complicated, and can include use of a specific chelating agent called deferoxamine to bind and expel excess iron from the body.

The role of iron in cancer defense can be described as a "double-edged sword" because of its pervasive presence in non-pathological processes. From Wikipedia, the free encyclopedia.

This article is about the metallic element. For other uses, see Iron disambiguation. Chemical element with atomic number Main article: Allotropes of iron.

Main article: Isotopes of iron. See also: Category:Iron compounds. Structural formula of ferrocene and a powdered sample.

Main article: History of ferrous metallurgy. Main article: Wrought iron. Further information: Ancient iron production.

Main article: Cast iron. Main article: Steel. See also: Steelmaking. See also: Iron ore. Main article: Blast furnace. Main articles: Steelmaking and Ironworks.

Main article: Thermite. See also: Steel. Main article: Human iron metabolism. Main article: Iron deficiency. Main article: Iron overload. Chemistry portal.

Pure and Applied Chemistry. Journal of Molecular Spectroscopy. Bibcode : JMoSp. Zeitschrift für anorganische und allgemeine Chemie. Physical Chemistry Chemical Physics.

Bibcode : PCCP April Retrieved 6 March American Association for the Advancement of Science. Journal of Physics. IOP Publishing. Reviews of Geophysics.

American Geophysical Union. Bibcode : RvGeo.. Journal of Geophysical Research: Solid Earth. Bibcode : JGR Mineral Physics.

Treatise on Geophysics. Theory and Calculation of Electric Circuits. Graham Introduction to Magnetic Materials, 2nd. Metallographer's guide: practice and procedures for irons and steels.

ASM International. Physical Review Letters. Bibcode : PhRvL. Mass Spectrometry Reviews. Bibcode : MSRv Archived from the original PDF on 10 June New Astronomy Reviews.

Bibcode : NewAR.. American Journal of Physics. Bibcode : AmJPh.. Nature Physics. Bibcode : NatPh The Astrophysical Journal Letters.

Bibcode : ApJ Bulletin of the American Astronomical Society. Bibcode : AAS Reviews of Modern Physics. Bibcode : RvMP New Scientist.

Retrieved 2 October Materials Characterization. Planet earth: cosmology, geology, and the evolution of life and environment.

Cambridge University Press. Bibcode : pecg. Earth and Planetary Science Letters. Bibcode : Natur. Bibcode : Sci Bibcode : PNAS Retrieved 7 July Hurlbut, Jr.

Economic Geology. London: Methuen. Minerva Stone Conservation. Retrieved 22 September Hyperfine Interactions.

Bibcode : HyInt. Inorganic Chemistry. Accounts of Chemical Research. Lehrbuch der Anorganischen Chemie in German 91— ed.

Walter de Gruyter. Mössbauer spectroscopy applied to inorganic chemistry. Cyanotype: the history, science and art of photographic printing in Prussian blue.

Hand-book of chemistry. Cavendish Society. A comparison of the X-ray crystal structures and low temperature magnetism of tetrakis methylammonium hexachloroferrate III chloride I and tetrakis hexamethylenediammonium hexachloroferrate III tetrachloroferrate III tetrachloride II ".

Inorganica Chimica Acta. Bis[ethylenebis diphenylphosphine ]-Hydridoiron Complexes. Inorganic Syntheses. Korean Chem.

Bibcode : PCM Chemistry of the Elements. Oxford: Pergamon Press. European Journal of Inorganic Chemistry. Retrieved 12 September Retrieved 7 August Lewis; Charles Short A Latin Dictionary.

Humans need 10—18 milligrams of iron each day. A lack of iron will cause anaemia to develop. Natural abundance. The core of the Earth is thought to be largely composed of iron with nickel and sulfur.

The most common iron-containing ore is haematite, but iron is found widely distributed in other minerals such as magnetite and taconite.

Commercially, iron is produced in a blast furnace by heating haematite or magnetite with coke carbon and limestone calcium carbonate. Around 1. Help text not available for this section currently.

Elements and Periodic Table History. Iron objects have been found in Egypt dating from around BC. They contain about 7.

The Iron Age had begun. Some kinds of iron were clearly superior to others depending on its carbon content, although this was not appreciated.

Some iron ore contained vanadium producing so-called Damascene steel, ideal for swords. This explained how steel, wrought iron, and cast iron, were to be distinguished by the amount of charcoal carbon they contained.

The Industrial Revolution which began that same century relied extensively on this metal. Atomic data. Glossary Common oxidation states The oxidation state of an atom is a measure of the degree of oxidation of an atom.

Oxidation states and isotopes. Glossary Data for this section been provided by the British Geological Survey. Relative supply risk An integrated supply risk index from 1 very low risk to 10 very high risk.

Recycling rate The percentage of a commodity which is recycled. Substitutability The availability of suitable substitutes for a given commodity.

Reserve distribution The percentage of the world reserves located in the country with the largest reserves.

Political stability of top producer A percentile rank for the political stability of the top producing country, derived from World Bank governance indicators.

Political stability of top reserve holder A percentile rank for the political stability of the country with the largest reserves, derived from World Bank governance indicators.

Supply risk. Relative supply risk 5. Young's modulus A measure of the stiffness of a substance. Shear modulus A measure of how difficult it is to deform a material.

Bulk modulus A measure of how difficult it is to compress a substance. Vapour pressure A measure of the propensity of a substance to evaporate.

Pressure and temperature data — advanced. Listen to Iron Podcast Transcript :. You're listening to Chemistry in its element brought to you by Chemistry World , the magazine of the Royal Society of Chemistry.

Hello, this week we turn to one of the most important elements in the human body. It's the one that makes metabolism possible and don't we just know it.

There are iron man challenges, iron fisted leaders and those said to have iron in the soul. But there's a dark side to element number 26 too because its powerful chemistry means that it's also bad news for brain cells as Nobel Laureate Kary Mullis explains.

For the human brain, iron is essential yet deadly. This change from the relatively plentiful and soluble FeII, took a heavy toil on almost everything alive at the time.

Surviving terrestrial and ocean-dwelling microbes developed soluble siderophore molecules to regain access to this plentiful, but otherwise inaccessible essential resource, which used hydroxamate or catechol chelating groups to bring the FeIII back into solution.

Eventually higher organisms including animals, evolved. And animals used the energy of oxygen recombining with the hydrocarbons and carbohydrates in plant life to enable motion.

Iron was essential to this process. But no animal, however, has been able to adequately deal, in the long run - meaning eighty year life spans - with the fact that iron is essential for the conversion of solar energy to movement, but is virtually insoluble in water at neutral pH, and, even worse, is toxic.

Carbon, sulfur, nitrogen. Iron does. Systems have evolved to maintain iron in specific useful and safe configurations - enzymes which utilize its catalytic powers, or transferrins and haemosiderins, which move it around and store it.

But these are not perfect. Sometimes iron atoms are misplaced, and there are no known systems to recapture iron that has precipitated inside of a cell.

In some tissues, cells overloaded with iron can be recycled or destroyed - but this doesn't work for neurons.

Neurons sprout thousands of processes during their existence - reaching out to form networks of connections to other neurons. During development of the adult human brain a large percentage of cells are completely eliminated, and some new ones are added.

It is a learning process. But once an area of the brain is up and running, there is nothing that can be done biologically, if a large number of its cells stop working for any reason.

And the slow creep of precipitating iron over many decades is perhaps most often that reason. In less sophisticated tissues, like the liver, new stem cells can be activated, but in the brain, trained, structurally complex, interconnected neurons are needed, with thousands of projections that are accumulated over a lifetime of learning.

So the result is slowly progressive neurodegenerative disease, like Parkinson's and Alzheimer's. This same basic mechanism can result in a variety of diseases.

There are twenty or thirty proteins that that deal with iron in the brain - holding iron and passing it from place to place.

Every new individual endowed with a new set of chromosomes is endowed with a new set of these proteins. Some combinations will be better than others and some will be dangerous individually and collectively.

A mutation in a gene that codes for one of these proteins could disrupt its function - allowing iron atoms to become lost. These atoms that have been lost from the chemical groups that hold them will not always be safely returned to some structure like transferrin or haemoferritin.

Some of them will react with water and be lost forever. Only they aren't really lost. They are piling up in the unlucky cell types that were the designated locations for expression of the most iron-leaky proteins.

And oxides of iron are not just taking up critical space. Iron is very reactive. The infamous "Reactive Oxygen Species" which have been suspected of causing so many age related illnesses may just derive from various forms of iron.

It is time for specialists trained in chemistry, and with an eye to the chemistry of iron, to pay some attention to neurodegenerative disease.

Kary Mullis telling the story of iron, the element that we can't do without, but which at the same time could hold the key to our neurological downfall.

Next time on Chemistry in its Element Johnny Ball will tell the story of Marie Curie and the element that she discovered and then named after her homeland.

Pitchblende, a uranium bearing ore, seemed to be far too radio active than could be accounted for by the uranium. They sieved and sorted by hand ounce by ounce through tons of pitchblende in a drafty, freezing shed, before eventually tiny amounts of polonium were discovered.

So be radioactive or at least podcast proactive and join us for the mysterious story of Polonium on next week's Chemistry in its Element. I'm Chris Smith, thank you for listening, see you next time.

View videos about. Help Text. Learn Chemistry : Your single route to hundreds of free-to-access chemistry teaching resources. We hope that you enjoy your visit to this Site.

We welcome your feedback. Data W. Haynes, ed. Version 1. Coursey, D. Schwab, J. Tsai, and R. Dragoset, Atomic Weights and Isotopic Compositions version 4.

Periodic Table of Videos , accessed December Podcasts Produced by The Naked Scientists. Download our free Periodic Table app for mobile phones and tablets.

Explore all elements. D Dysprosium Dubnium Darmstadtium. E Europium Erbium Einsteinium. F Fluorine Francium Fermium Flerovium.

G Gallium Germanium Gadolinium Gold. I Iron Indium Iodine Iridium. K Krypton. O Oxygen Osmium Oganesson.

U Uranium. V Vanadium. X Xenon. Y Yttrium Ytterbium. Z Zinc Zirconium. Membership Become a member Connect with others Supporting individuals Supporting organisations Manage my membership.

Facebook Twitter LinkedIn Youtube. Discovery date. Discovered by. Origin of the name. The name comes from the Anglo-Saxon name 'iren'.

Melting point. Boiling point. Atomic number. Relative atomic mass. Key isotopes. Electron configuration. CAS number. ChemSpider ID.

ChemSpider is a free chemical structure database. Electronegativity Pauling scale. Common oxidation states.

Iron Table Holztisch, er 1. Eisengottestisch abgetrennt. Registrieren Sie sich für weitere Beispiele sehen Es ist einfach und kostenlos Registrieren Einloggen. Clear filters. Interkontinentale Lieferungen können zur maximalen Sicherheit in Holzkisten erfolgen. Häkchen Icon Zu Ihrem Warenkorb hinzugefügt:. Yang Jingfang, who is near 60 years Stargames Kein Paypal Mehr, they handcuffed her onto an iron table for 32 days, resulting in oedema over large parts of her body. Inside Villa Giada there is a restaurant that makes breakfast and dinner service. Marken Neuzugänge Geschenke. Was this helpful?


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